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He didn't purposely turn his skin blue - it's a side effect from the colloidal silver, generally due to making it wrong or taking WAY too much of it. Many people who are into alternative health treatments get a little obsessive with it and put too much stock into it - I think that's probably what he's done. It is extremely rare with people who take colloidal silver because you basically have to overdose on it in order for that to happen. It doesn't happen to everyone who takes it (my dad and sister have both taken it, and I think there's a bottle in the fridge at my house right now), but it's a risk, especially if you take a lot of it.
It's likely the corpse skin lady had too much exposure to sunlight after getting that effect - sunlight darkens the colour and can basically turn you black if you're already blue from colloidal silver.
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