If your pictures are unaltered, your actual screen resolution of 1024x576 is 16:9 (not 16:10)
Your physical screen resolution might be 16:10 (let me guess, the famous 1440x900?) but your in-game resolution is 16:9, which gives a larger image (proportionally speaking). If I'm right, you probably have slight black bars at top and bottom of the game, or your Sims appear slimmer than they should (they are stretched vertically).
I do have a 1440x900 screen (16:10), but the game only offers me 1280x768 (16:9.6) for WS. When comparing my screenshots with yours, I have slightly more place on the left of the box (the one where you enter Sim settings) and much less on the right. The default Maxis camera settings, while causing the Sim to be off-centered, does not cause it to be partially hidden as on your screenshots. In fact, I find that only pets (which your config file does not affect) are a problem on my CAS screens.
Therefore your camera settings do not work well for me.
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