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You can learn a fair bit about editing UI elements from the thread about UI recolours:
https://modthesims.info/t/553732
The UI is made up of IMAG textures and LAYO xmls, the most difficult part mostly being locating the file you need.
Most of them are named, but whether EA's naming conventions point you in the right direction can vary.
You may be able to narrow your search by trying out a few of the existing UI recolours out there and seeing if any of them change those trait outlines- because if they do, you at least know the right file is in their package vs combing the game files in their entirety.
S3PE can preview image, so you can pan through the IMAG until you find what you're looking for